In the beginning of the famous dance of the two main characters at the Netherfield ball (before the conversation has started) you can see a short shot showing how Lizzy with a sweet smile is passing along Darcy, as if she has just heard something very funny. This smile contrasts with her facial expression in the shots before and after that.
Probably after the incident with the hair they were short of good shots and have used this one as a filler... I don't mind, JE has a pretty smile. :-)